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Possible Answers: DAP.
Last seen on: NY Times Crossword 23 Aug 2018, Thursday
Random information on the term “DAP”:
Diamidophosphate (DAP) is a phosphorylating ion, with formula PO2(NH2)2− and was first used for phosphorylation of sugars in aqueous medium.[1] Diamidophosphate can form salts such as sodium diamidophosphate, or an acid phosphorodiamidic acid. Phosphorodiamidic acid can crystallize as a trihydrate.[2] It is hypothesized as a plausible primordial reagent in the emergence of the first peptides, cell membrane lipids and nucleotides, the precursors of all life on Earth.[3] In a November 6, 2017 press release from the Scripps Research Institute, DAP was described as “a compound that may have been a crucial factor in the origins of life on Earth”.[4] Other nitrogenous derivatives of phosphorus derivatives have also been proposed in this context in a review article.[5]
Diamidophosphate compounds can be made from phenyl diamidophosphate (phenylphosphorodiamidate) reacting with sodium hydroxide in a water solution. This solution can crystallise sodium diamidophosphate. Phosphorodiamidic acid trihydrate can be precipitated from the solution by adding it to an excess of ethanol.[2]