Fist bump, colloquially

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DAP.

Last seen on: Premier Sunday – King Feature Syndicate Crossword – Jan 6 2019

Random information on the term “DAP”:

Diamidophosphate (DAP) is the simplest phosphorodiamidate ion, with formula PO2(NH2)2−. It is a phosphorylating ion and was first used for phosphorylation of sugars in aqueous medium.[1] Diamidophosphate can form salts such as sodium diamidophosphate, or an acid phosphorodiamidic acid. Phosphorodiamidic acid can crystallize as a trihydrate.[2] It is hypothesized as a plausible primordial reagent in the emergence of the first peptides, cell membrane lipids and nucleotides, the precursors of all life on Earth.[3] In a November 6, 2017 press release from the Scripps Research Institute, DAP was described as “a compound that may have been a crucial factor in the origins of life on Earth”.Cite error: The <ref> tag has too many names (see the help page). Other nitrogenous derivatives of phosphorus derivatives have also been proposed in this context in a review article.[4]

Diamidophosphate compounds can be made from phenyl diamidophosphate (phenylphosphorodiamidate) reacting with sodium hydroxide in a water solution. This solution can crystallise sodium diamidophosphate. Phosphorodiamidic acid trihydrate can be precipitated from the solution by adding it to an excess of ethanol.[2]

DAP on Wikipedia